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Please Help Me Create This Effect in Photoshop.

Photo wizards,

How does one mess with the colors so they become as such?: 

Please Help Me Create This Effect in Photoshop.

 

Am I correct in thinking the process is similiar in both photos? (They're by the same artist.) I have a pretty capable camera. I realize the exposure is great, but I certainly see some processing as well.

Any ideas?

Thanks.

Photos from b109.com 

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